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An elementary reaction is a reaction for which no Reaction Intermediates have been detected or need to be postulated in order to describe the chemical reaction on a molecular scale. An elementary reaction is assumed to occur in a single step and to pass through a single Transition State.

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A molecular entity is any constitutionally or isotopically distinct atom, molecule, radical, complex, conformer etc., identifiable as a separately distinguishable entity.

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A chemical species is an ensemble of chemically identical molecular entities (on the time scale of the observation).

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A substituent is an atom or group of bonded atoms that can be considered to have replaced a hydrogen atom (or two hydrogen atoms in the special case of bivalent groups) in a ...

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